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<title lang=en>Trace element behavior during serpentinization/de-serpentinization of an eclogitized oceanic lithosphere: A LA-ICPMS study of the Lanzo ultramafic massif (Western Alps)</title>
<creator>Debret, Baptiste</creator>
<creator>Andreani, Muriel</creator>
<creator>Godard, Marguerite</creator>
<creator>Nicollet, Christian</creator>
<creator>Schwartz, Stephane</creator>
<creator>Lafay, Romain</creator>
<contributor>Laboratoire Magmas et Volcans (LMV) ; Université Blaise Pascal - Clermont-Ferrand 2 (UBP) - Institut national des sciences de l'Univers (INSU - CNRS) - Université Jean Monnet [Saint-Étienne] (UJM) - Centre National de la Recherche Scientifique (CNRS)</contributor>
<contributor>Laboratoire de Géologie de Lyon - Terre, Planètes, Environnement [Lyon] (LGL-TPE) ; École normale supérieure - Lyon (ENS Lyon) - Université Claude Bernard Lyon 1 (UCBL) - Institut national des sciences de l'Univers (INSU - CNRS) - Centre National de la Recherche Scientifique (CNRS)</contributor>
<contributor>Manteau et Interfaces ; Géosciences Montpellier ; Université des Antilles et de la Guyane (UAG) - Institut national des sciences de l'Univers (INSU - CNRS) - Université de Montpellier (UM) - Centre National de la Recherche Scientifique (CNRS) - Université des Antilles et de la Guyane (UAG) - Institut national des sciences de l'Univers (INSU - CNRS) - Université de Montpellier (UM) - Centre National de la Recherche Scientifique (CNRS)</contributor>
<contributor>Institut des Sciences de la Terre (ISTerre) ; Université Joseph Fourier - Grenoble 1 (UJF) - Institut Français des Sciences et Technologies des Transports, de l'Aménagement et des Réseaux (IFSTTAR) - Institut national des sciences de l'Univers (INSU - CNRS) - Institut de recherche pour le développement [IRD] : UR219 - PRES Université de Grenoble - Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry]) - Centre National de la Recherche Scientifique (CNRS)</contributor>
<description>International audience</description>
<source>ISSN: 0009-2541</source>
<source>Chemical Geology</source>
<publisher>Elsevier</publisher>
<identifier>hal-00937661</identifier>
<identifier>https://hal.archives-ouvertes.fr/hal-00937661</identifier>
<source>https://hal.archives-ouvertes.fr/hal-00937661</source>
<source>Chemical Geology, Elsevier, 2013, 357, pp.117-133. 〈10.1016/j.chemgeo.2013.08.025〉</source>
<identifier>DOI : 10.1016/j.chemgeo.2013.08.025</identifier>
<relation>info:eu-repo/semantics/altIdentifier/doi/10.1016/j.chemgeo.2013.08.025</relation>
<language>en</language>
<subject lang=en>Lizardite</subject>
<subject lang=en>Antigorite</subject>
<subject lang=en>Trace element</subject>
<subject lang=en>Oceanic lithosphere</subject>
<subject lang=en>Subduction</subject>
<subject>[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry</subject>
<subject>[SDE.MCG] Environmental Sciences/Global Changes</subject>
<type>info:eu-repo/semantics/article</type>
<type>Journal articles</type>
<description lang=en>Serpentinites are one of the major components of the oceanic lithosphere and are stable in the slab and the mantle wedge up to 100-150 km depth in subduction zones. During oceanic mantle hydration and alteration, they trap trace and fluid mobile (FME: B, Li, As, Sb, Rb, Ba, Cs, Sr, U and Pb) elements that participate to elemental transfer occurring between the dehydrating slab and the mantle wedge in subduction context. The Lanzo massif is an eclogitized oceanic lithosphere that preserved its oceanic structure and recorded different steps of serpentinization/de-serpentinization from oceanic lizardite to prograde antigorite in subduction context, up to its dehydration and secondary olivine crystallization, and finally retrograde antigorite during massif exhumation. It constitutes a suitable place to study trace element behavior during serpentinization/de-serpentinization processes and associated chemical transfers between the different envelopes of the oceanic lithosphere and the mantle wedge. Geochemical analyses of serpentine and associated minerals show that the serpentinization/de-serpentinization of the Lanzo massif took place in a relatively closed system without significant trace element transfer between the different parts of the oceanic lithosphere. In the deeper part of the lithosphere, from the slightly serpentinized mantle peridotites (SSP, < 20% serpentinization) to the paleo-Moho, composed of massive serpentinites (MS, 80% serpentinization), the trace elements mobility is reduced. The chemical composition of lizardite and antigorite is homogenized with the local degree of serpentinization: in SSP, serpentine veins composition is inherited from the host mineral while, in MS, their composition is homogenous between destabilized phases at the scale of the outcrop (~ 5 m). In the shallowest part of the oceanic lithosphere, from the paleo-Moho to the oceanic paleo-seafloor, the serpentinites are foliated (FS, > 90% serpentinization). In that zone, the alpine deformation enhances the mobility of trace elements and permits their redistribution and the homogenization of antigorite composition at massif scale. Locally, in the SSP and MS, the crystallization of metamorphic veins of ~ 1-2 m corresponds to channelized fluid flows that allowed fluid transfers - and thereby trace elements - to longer distance. The successive crystallizations of antigorite and then olivine are accompanied by a diminution of some FME (B, Li, As, Sb, Ba, Rb) and Eu contents attesting that these elements are removed from slab to mantle wedge during subduction.</description>
<date>2013-10-24</date>
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