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<title lang=en>Decrease of hydrogen incorporation in forsterite from CO2-H2O-rich kimberlitic liquid</title>
<creator>BAPTISTE, Virginie</creator>
<creator>Demouchy, Sylvie</creator>
<creator>Keshav, Shantanu</creator>
<creator>Parat, Fleurice</creator>
<creator>Bolfan-Casanova, Nathalie</creator>
<creator>Condamine, Pierre</creator>
<creator>Cordier, Patrick</creator>
<contributor>Géosciences Montpellier ; Université des Antilles et de la Guyane (UAG) - Institut national des sciences de l'Univers (INSU - CNRS) - Université de Montpellier (UM) - Centre National de la Recherche Scientifique (CNRS)</contributor>
<contributor>Manteau et Interfaces ; Géosciences Montpellier ; Université des Antilles et de la Guyane (UAG) - Institut national des sciences de l'Univers (INSU - CNRS) - Université de Montpellier (UM) - Centre National de la Recherche Scientifique (CNRS) - Université des Antilles et de la Guyane (UAG) - Institut national des sciences de l'Univers (INSU - CNRS) - Université de Montpellier (UM) - Centre National de la Recherche Scientifique (CNRS)</contributor>
<contributor>Laboratoire Magmas et Volcans (LMV) ; Université Blaise Pascal - Clermont-Ferrand 2 (UBP) - Institut national des sciences de l'Univers (INSU - CNRS) - Université Jean Monnet [Saint-Étienne] (UJM) - Centre National de la Recherche Scientifique (CNRS)</contributor>
<contributor>Unité Matériaux et Transformations - UMR 8207 (UMET) ; Centre National de la Recherche Scientifique (CNRS) - Ecole Nationale Supérieure de Chimie de Lille (ENSCL) - Institut National de la Recherche Agronomique (INRA) - Université de Lille, Sciences et Technologies</contributor>
<description>International audience</description>
<source>ISSN: 0003-004X</source>
<source>American Mineralogist</source>
<publisher>Mineralogical Society of America</publisher>
<identifier>hal-01217157</identifier>
<identifier>https://hal.archives-ouvertes.fr/hal-01217157</identifier>
<source>https://hal.archives-ouvertes.fr/hal-01217157</source>
<source>American Mineralogist, Mineralogical Society of America, 2015, 100 (8-9), pp.1912-1920. 〈10.2138/am-2015-5200〉</source>
<identifier>DOI : 10.2138/am-2015-5200</identifier>
<relation>info:eu-repo/semantics/altIdentifier/doi/10.2138/am-2015-5200</relation>
<language>en</language>
<subject lang=en>Kimberlite</subject>
<subject lang=en>water</subject>
<subject lang=en>hydrogen</subject>
<subject lang=en>diffusion</subject>
<subject lang=en>olivine</subject>
<subject lang=en>point defect</subject>
<subject>[SDU.STU.PE] Sciences of the Universe [physics]/Earth Sciences/Petrography</subject>
<type>info:eu-repo/semantics/article</type>
<type>Journal articles</type>
<description lang=en>To test if hydrogen incorporation by ionic diffusion can occur between a volatile-rich kimberlitic liquid and forsterite, results of high-pressure and high-temperature experiments using a piston-cylinder apparatus at 1200–1300 °C and 1 GPa for durations of 1 min, 5 h, and 23 h, are reported here. Kimberlitic liquid in the system CaO-MgO-Al2O3-SiO2-CO2-H2O and synthetic forsterite single crystals were chosen as a first simplification of the complex natural kimberlite composition. Unpolarized Fourier transform infrared spectroscopy was used to quantify the concentrations of OH in the crystallographically oriented forsterite. Scanning electron microscopy, electron backscattered diffraction, electron microprobe analyses, and transmission electron microscopy were performed to identify the run products. After 5 and 23 h, a forsterite overgrowth crystallized with the same orientation as the initial forsterite single crystal. The kimberlitic liquid has crystallized as micrometer-scale euhedral forsterite neocrystals with random crystallographic orientations, as well as a nanoscale aluminous phase and a calcic phase. Despite theoretical water-saturation of the system and long duration, none of the initial forsterite single crystals display signs of hydration such as hydrogen diffusion profile from the border toward the center of the crystal. Most likely, the presence of CO2 in the system has lowered the H2O fugacity to such an extent that there is no significant hydration of the starting forsterite single crystal or its overgrowth. Also, the presence of CO2 enhances rapid forsterite crystal growth. Forsterite growth rate is around 2 × 108 μm3/h at 1250 °C. These experimental results suggest a deep mantle origin of the high OH content found in natural mantle-derived xenoliths transported in kimberlites, as reported from the Kaapvaal craton. In agreement with previous studies, it also points out to the fact that significant hydration must take place in a CO2-poor environment.</description>
<date>2015</date>
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