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<title lang=en>Geochemistry of subduction zone serpentinites: A review</title>
<creator>Deschamps, Fabien</creator>
<creator>Godard, Marguerite</creator>
<creator>Guillot, Stephane</creator>
<creator>Hattori, Keiko</creator>
<contributor>Manteau et Interfaces ; Géosciences Montpellier ; Université des Antilles et de la Guyane (UAG) - Institut national des sciences de l'Univers (INSU - CNRS) - Université de Montpellier (UM) - Centre National de la Recherche Scientifique (CNRS) - Université des Antilles et de la Guyane (UAG) - Institut national des sciences de l'Univers (INSU - CNRS) - Université de Montpellier (UM) - Centre National de la Recherche Scientifique (CNRS)</contributor>
<contributor>Institut des Sciences de la Terre (ISTerre) ; Université Joseph Fourier - Grenoble 1 (UJF) - Institut Français des Sciences et Technologies des Transports, de l'Aménagement et des Réseaux (IFSTTAR) - Institut national des sciences de l'Univers (INSU - CNRS) - Institut de recherche pour le développement [IRD] : UR219 - PRES Université de Grenoble - Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry]) - Centre National de la Recherche Scientifique (CNRS)</contributor>
<contributor>Department of Earth Sciences, University of Ottawa ; Université du Québec</contributor>
<description>International audience</description>
<source>ISSN: 0024-4937</source>
<source>Lithos</source>
<publisher>Elsevier</publisher>
<identifier>hal-00903601</identifier>
<identifier>https://hal.archives-ouvertes.fr/hal-00903601</identifier>
<source>https://hal.archives-ouvertes.fr/hal-00903601</source>
<source>Lithos, Elsevier, 2013, 178, pp.96-127. 〈10.1016/j.lithos.2013.05.019〉</source>
<identifier>DOI : 10.1016/j.lithos.2013.05.019</identifier>
<relation>info:eu-repo/semantics/altIdentifier/doi/10.1016/j.lithos.2013.05.019</relation>
<language>en</language>
<subject lang=en>Abyssal peridotites</subject>
<subject lang=en>Serpentine phases</subject>
<subject lang=en>Subduction zones</subject>
<subject lang=en>Geochemistry</subject>
<subject lang=en>Mantle wedge serpentinites</subject>
<subject lang=en>Subducted serpentinites</subject>
<subject>[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry</subject>
<subject>[SDE.MCG] Environmental Sciences/Global Changes</subject>
<type>info:eu-repo/semantics/article</type>
<type>Journal articles</type>
<description lang=en>Over the last decades, numerous studies have emphasized the role of serpentinites in the subduction zone geodynamics. Their presence and role in subduction environments are recognized through geophysical, geochemical and field observations of modern and ancient subduction zones and large amounts of geochemical database of serpentinites have been created. Here, we present a review of the geochemistry of serpentinites, based on the compilation of ~ 900 geochemical data of abyssal, mantle wedge and exhumed serpentinites after subduction. The aim was to better understand the geochemical evolution of these rocks during their subduction as well as their impact in the global geochemical cycle. When studying serpentinites, it is essential to determine their protoliths and their geological history before serpentinization. The geochemical data of serpentinites shows little mobility of compatible and rare earth elements (REE) at the scale of hand-specimen during their serpentinization. Thus, REE abundance can be used to identify the protolith for serpentinites, as well as magmatic processes such as melt/rock interactions before serpentinization. In the case of subducted serpentinites, the interpretation of trace element data is difficult due to the enrichments of light REE, independent of the nature of the protolith. We propose that enrichments are probably not related to serpentinization itself, but mostly due to (sedimentary-derived) fluid/rock interactions within the subduction channel after the serpentinization. It is also possible that the enrichment reflects the geochemical signature of the mantle protolith itself which could derive from the less refractory continental lithosphere exhumed at the ocean-continent transition. Additionally, during the last ten years, numerous analyses have been carried out, notably using in situ approaches, to better constrain the behavior of fluid-mobile elements (FME; e.g. B, Li, Cl, As, Sb, U, Th, Sr) incorporated in serpentine phases. The abundance of these elements provides information related to the fluid/rock interactions during serpentinization and the behavior of FME, from their incorporation to their gradual release during subduction. Serpentinites are considered as a reservoir of the FME in subduction zones and their role, notably on arc magma composition, is underestimated presently in the global geochemical cycle.</description>
<date>2013-09-15</date>
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