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<title lang=en>In situ characterization of serpentinites from forearc mantle wedges: Timing of serpentinization and behavior of fluid-mobile elements in subduction zones</title>
<creator>Deschamps, Fabien</creator>
<creator>Guillot, Stephane</creator>
<creator>Godard, Marguerite</creator>
<creator>Chauvel, Catherine</creator>
<creator>Andreani, Muriel</creator>
<creator>Hattori, Kiko</creator>
<contributor>Laboratoire de Géodynamique des Chaines Alpines (LGCA) ; Observatoire des Sciences de l'Univers de Grenoble (OSUG) ; Université Joseph Fourier - Grenoble 1 (UJF) - Institut national des sciences de l'Univers (INSU - CNRS) - Centre National de la Recherche Scientifique (CNRS) - Université Joseph Fourier - Grenoble 1 (UJF) - Institut national des sciences de l'Univers (INSU - CNRS) - Centre National de la Recherche Scientifique (CNRS) - Institut des Sciences de la Terre (ISTerre) ; Université Joseph Fourier - Grenoble 1 (UJF) - Institut Français des Sciences et Technologies des Transports, de l'Aménagement et des Réseaux (IFSTTAR) - Institut national des sciences de l'Univers (INSU - CNRS) - Institut de recherche pour le développement [IRD] : UR219 - PRES Université de Grenoble - Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry]) - Centre National de la Recherche Scientifique (CNRS) - Institut Français des Sciences et Technologies des Transports, de l'Aménagement et des Réseaux (IFSTTAR) - Institut de recherche pour le développement [IRD] : UR219 - PRES Université de Grenoble - Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry]) - Centre National de la Recherche Scientifique (CNRS)</contributor>
<contributor>Géosciences Montpellier ; Université des Antilles et de la Guyane (UAG) - Institut national des sciences de l'Univers (INSU - CNRS) - Université de Montpellier (UM) - Centre National de la Recherche Scientifique (CNRS)</contributor>
<contributor>Laboratoire de Sciences de la Terre (LST) ; École normale supérieure - Lyon (ENS Lyon) - Université Claude Bernard Lyon 1 (UCBL) - Institut national des sciences de l'Univers (INSU - CNRS) - Centre National de la Recherche Scientifique (CNRS)</contributor>
<contributor>Department of Earth Science ; University of Ottawa</contributor>
<contributor>PROCOPE ; CNRS INSU</contributor>
<description>International audience</description>
<source>ISSN: 0009-2541</source>
<source>Chemical Geology</source>
<publisher>Elsevier</publisher>
<identifier>hal-00475565</identifier>
<identifier>https://hal.archives-ouvertes.fr/hal-00475565</identifier>
<source>https://hal.archives-ouvertes.fr/hal-00475565</source>
<source>Chemical Geology, Elsevier, 2010, 269 (3-4), pp.262-277. 〈10.1016/j.chemgeo.2009.10.002〉</source>
<identifier>DOI : 10.1016/j.chemgeo.2009.10.002</identifier>
<relation>info:eu-repo/semantics/altIdentifier/doi/10.1016/j.chemgeo.2009.10.002</relation>
<language>en</language>
<subject lang=en>High-pressure serpentines</subject>
<subject lang=en>Forearc mantle peridotites</subject>
<subject lang=en>Subduction zones</subject>
<subject lang=en>Hydrated mantle wedge</subject>
<subject lang=en>Fluid-mobile elements recycling</subject>
<subject>[SDU.STU.PE] Sciences of the Universe [physics]/Earth Sciences/Petrography</subject>
<type>info:eu-repo/semantics/article</type>
<type>Journal articles</type>
<description lang=en>The Tso Morari serpentinites in the Ladakh area, northwest Himalaya, originated from the forearc mantle overlying the northward subducting Neo-Tethys lithosphere and the margin of the Indian continent. The serpentinites are characterized by high concentration of fluid-mobile elements (FME: As, Sb, B, Li, and U) compared to ophiolitic or abyssal serpentinites. The Pb isotopic compositions of serpentinites show influence of the subducted Indian continental lithosphere. Trace element concentrations of antigorite determined in situ with Laser Ablation High Resolution Inductively Coupled Mass Spectrometer (LA-HR-ICP-MS) show high contents of FME including Pb, in contrast to the spatially associated iron oxides. Rare earth elements (REE) and compatible elements, such as Sc and Co, remained immobile during the hydration, allowing the identification of the primary minerals (olivine or orthopyroxene) from which serpentine formed. Serpentinized olivine displays higher Sb and As concentrations (up to 1000 x PM) than serpentinized orthopyroxenes that are enriched in Pb, Cs and Li (2 to up to 10 x PM).;We propose that the observed FME distribution in two types of serpentine reflect the differential incorporation of FME during the downward movement of the serpentinite along the subduction plane. At temperature lower than 400 degrees C, at shallow depths, olivine is preferentially serpentinized and incorporates elements that are fluid soluble at low temperatures, such as Sb and As. Above 400 degrees C, orthopyroxene is hydrated and incorporates Pb, Cs, Li and possibly Ba. Boron and U are incorporated in both types of serpentine suggesting that they are released from slabs at temperatures around 300-400 degrees C. The serpentine acts as a sink for water, but also for FME and transports them to deeper and hotter levels in the mantle, down to the isotherm 600-650 degrees C where dehydration occurs.</description>
<date>2010-01-30</date>
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